With the addition of CaO, the basicity of LF slag gets higher, the sulfur capacity of LF slag increases, desulphurizing capacity goes up. When the basicity of LF slag reaches a certain value, if it continue increasing, CaO content in LF slag gets higher, then the viscosity of slag also gets higher, the sulfer diffusion at slag-steel interface becomes a restrictive link, which makes the dynamics condition of slag desulfurization poor, at this stage, improving slag basicity would lower make desulfurization degree.